Front Cover: N -Difluorocyclopropyl-Substituted Pyrazoles: Synthesis and Reactivity (Eur. J. Org. Chem. 27/2019)
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چکیده
منابع مشابه
Microwave Synthesis of Arylmethyl Substituted Pyrazoles
The synthesis under MW irradiation without solvent of 19 pyrazoles, of which only 8 were known, is described. They bear C-methyl groups and trityl, diphenylmethyl and benzyl groups at positions 1 and 4 of the pyrazole ring. In the reaction between pyrazole and trityl bromide an unexpected reaction occurred and 4-(9-phenyl-9H-fluoren-9-yl)-1Hpyrazole (7) was isolated.
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The dipolar cycloaddition reactivity of N-(1-naphthy1)-1,4- benzoquinoneimine N-oxide and N-phenyl-1,4- naphthoquinoneimine Noxide are investigated, The latter gives the expected adducts with common dipolarophiles such as acrylonitryle, methyl methacrylate, dimethylacetylene dicarboxylate and N-phenylmaleimide. The reactivity of the former nitrone is found to be minimal. It undergoes, how...
متن کاملSynthesis of 1,3,5-tri-substituted pyrazoles promoted by P2O5.SiO2
Silica supported phosphorus pentoxide (P2O5·SiO2) is an efficient catalyst for synthesis of 1,3,5-substituted pyrazoles via the condensation of 1,3-diketones and hydrazines. Simplicity of procedure, mild condition, being solvent-free, high yields, and easy workup are some advantages of this protocol.
متن کاملSynthesis of 1,3,5-tri-substituted pyrazoles promoted by P2O5.SiO2
Silica supported phosphorus pentoxide (P2O5·SiO2) is an efficient catalyst for synthesis of 1,3,5-substituted pyrazoles via the condensation of 1,3-diketones and hydrazines. Simplicity of procedure, mild condition, being solvent-free, high yields, and easy workup are some advantages of this protocol.
متن کاملsynthesis of 1,3,5-tri-substituted pyrazoles promoted by p2o5.sio2
silica supported phosphorus pentoxide (p2o5·sio2) is an efficient catalyst for synthesis of 1,3,5-substituted pyrazoles via the condensation of 1,3-diketones and hydrazines. simplicity of procedure, mild condition, being solvent-free, high yields, and easy workup are some advantages of this protocol.
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ژورنال
عنوان ژورنال: European Journal of Organic Chemistry
سال: 2019
ISSN: 1434-193X
DOI: 10.1002/ejoc.201900911